W ith the ratification of the montreal protocol in 1987, chlorofluorocarbon cfc and hydrochlorofluorocarbon hcfc refrigerants, such as r11, r12, r22, and r123, have been or will soon be phased out due to their high ozone depleting potential odp. The dispersion of refrigerants into the atmosphere contributes to destroying the ozone layer and thus to increases in the greenhouse effect responsible for global warming. Curbing them is key to climatechange strategy oped. This refrigeration playbook provides guidance to refrigeration system design teams about selecting energyefficient refrigeration systems that use lowglobal warming potential gwp refrigerants. This policy aims to minimize emissions of high global warming potential gwp refrigerants used in stationary nonresidential equipment through leak detection and monitoring, leak repair, system retrofit and retirement, and required service practices.
It is ashraelisted as an a1 refrigerant, meaning that it has no flame propagation at 63c. Because of the potential damage that refrigerants can do to the environment, section 609 of the clean air act caa directs epa to establish requirements to prevent the release of refrigerants during the servicing of mvacs and mvaclike appliances and to require recycling of used refrigerants. Natural refrigerants selecting and designing energyefficient commercial refrigeration systems that use low global warming potential refrigerants caleb nelson, chuck reis, eric nelson, james armer, rob arthur, richard heath, and james rono cta architects engineers boise, idaho adam hirsch and ian doebber. Carbon dioxide was chosen by the intergovernmental panel on climate. Greenhouse gases include carbon dioxide, methane, cfcs, hfcs, hcfcs and halons.
Report from the commission assessing the 2022 requirement to. The following table includes the 100year time horizon global warming potentials gwp relative to co2. Pdf natural and synthetic refrigerants, global warming. Motor vehicle air conditioning environmental impacts of mvac refrigerants ozone depletion potential global warming potential 1 0 0 0 0 cfc12 hfc4a hfc152a hfo1234yf co.
Demonstration and pilot activities for encouraging low. Global warming potential is a measurement of how much heat a greenhouse gas can trap within the atmosphere. Highgwp refrigerants california air resources board. Cfc emissions has also considerably decreased the global warming impact. The treatment by leed of the environmental impact of hvac. Global warming potential values the following table includes the 100year time horizon global warming potentials gwp relative to co2. Ahri low global warming potential alternative refrigerants. Carefully avoiding the noise of deliberate and unjustified bad publicity, a small but significant number of local and international companies decided quietly to adopt the concept of natural refrigerants anyway. Dissemination of nextgeneration refrigerants taking the. In view of the global warming potential of these newly synthesized refrigerants, the recent trend.
Assessment of commercially available energyefficient room air conditioners including models with low global warming potential gwp refrigerants. In addition to performing energy measurement and analysis of the existing systems in five pilot plants, the refrigerant used was changed with environmentally friendly alternatives. For the great majority of cases there are a number of different values of gwp for each specific refrigerant. Danfoss offers a broad product portfolio for refrigerants with low global warming potential low gwp. These molecules are hydrofluoroolefins hfo and honeywell has discovered that these molecules have an extremely low global warming potential gwp of only 4 to 6 as compared to 1430 for r. Hfcs with high global warming potential gwp will be. The montreal protocol has eliminated odp by requiring replacement of cfcs and hcfcs with hfcs such as r410a, r407c, and r4a. R407a has a global warming potential about 50% lower than r404a tables 2a and 2b show theoretical performance of freon 407c, freon 407a, and hcfc22. This table is adapted from the ipcc fifth assessment. This is due to a number of reasons, including the following. The next focus is a worldwide technical and policy search for nextgeneration refrigerants with low global warming potential lgwp. Limited options for lowglobalwarmingpotential refrigerants. In recent decades, the impact of refrigerants on the environment has become a major issue. Alternative refrigerants must replace the existing ones with fewer environmentally.
Due to the growing threat of climate change, usage of hfcs has been scrutinized in an attempt to. Reduce refrigerant leak to 10% per year, refrigerant gwp by 50%, and reduce charge by 65% 40% indirect warming impact energy consumption for large systems, global warming becomes an efficiency. Frequently asked questions ashrae safety classification of. Opteon xp40 is suitable for new installations, as well as. An evaluation of the environmental impact of different commercial supermarket refrigeration systems using low global warming potential refrigerants. Performance assessment of vapor compression systems.
Today, the environmental spotlight is shifting to the gwp of refrigerants. All books are in clear copy here, and all files are secure so dont worry about it. R410a, the most common air conditioning refrigerant in use globally today, is not actually nonflammable. Odp ozone depletion potential degree to which a substance can degrade the ozone layer. Refrigerants for lower global warming potential explore this whitepaper discusses the global trends within refrigeration and air conditioning. Calculation of global warming potential gwp v alues of refrigerants is a complex issue. Industrialized countries have already converted to hfcs hydrofluorocarbons refrigerants like r410a that dont deplete the ozone layer, but these still have the potential problem of having a high global warming impact. Nextgeneration low global warming potential refrigerants. Reduce refrigerant gwp by 50% 5% direct warming impact refrigerant leakage eliminate 55% of global warming impact reduce direct impact by 92% 3. Refrigerants r407c and r407a properties, uses, storage. Frequently asked questions ashrae safety classification of refrigerants toxicity is classified based on occupational exposure limit oel. Benefits of leapfrogging to superefficiency and low global warming potential refrigerants in room air conditioning nihar shah, max wei, virginie letschert, amol phadke. When scientists speak of the global warming impact of refrigerants, they generally.
On this scale, the gwp of a refrigerant such as hfc4a is 0. Ashrae standard 34 2019 lower global warming potential refrigerants. Department of energy under lawrence berkeley national laboratory contract no. Ozone depletion potential odp of a chemical compound is the relative amount of degradation it can cause to the ozone layer. By brian fricke, ken schultz, and xudong wang from the february 2017 issue. Energy and global warming impacts of hfc refrigerants and emerging technologies james r. Hfcs are commonly used as refrigerants and propellants in aerosols. By convention, the calculation integrates the effect from each gas over 100 years table 1.
A preliminary assessment of the existing systems in terms of energy efficiency has been made and the. Change ipcc as the reference gas and its gwp is taken as 1. Greenhouse gases like hfcs trap the suns heat, bringing unwanted changes to the earths environment. Refrigeration systems using low global warming potential refrigerants. Phaseout decision of hfc has been agreed in protocols meetings worldwide 3. Benefits of leapfrogging to superefficiency and low global warming potential refrigerants in room air conditioning.
Ozone depletion potential odp of a chemical compound is the relative amount of degradation it can cause to the ozone layerglobal warming potential gwp is a measure of how much a given mass of a gas contributes to global warming. Ahri low global warming potential alternative refrigerants evaluation program welcome to the conference orlando, fl january 21, 2016 2. Refrigerants containing chlorine or bromine contribute to the breakdown of the ozone layer see figure 5. Methods of calculating total equivalent warming impact. Ever since the montreal protocol agreed to phase out hydrochlorofluorocarbons hcfcs, there has been an increasing interest within the protocol on climate issues. It assigns a value to the amount of heat trapped by a certain mass of a gas relative to the amount of heat trapped by a similar mass of carbon dioxide over a specific period of time. Global warming and climate change are caused by the emission of greenhouse gases, which trap the outgoing heat from the earth causing the atmosphere to become warmer. Global warming potential gwp the global warming potential is an index that relates the potency of a greenhouse gas to that of carbon dioxide. Refrigerants regulated under the refrigerant management program rmp include any refrigerant that is an ozone depleting substance ods as defined in title 40 of the code of federal regulation, part 82, and any compound with a global warming potential gwp value equal to or greater than 150 according to the gwps specified in ipccs fourth assessment report of 2007. Refrigerants can thus also be ranked according to their impact on the stratospheric ozone layer the ozone depletion potential, odp or as greenhouse gases the global warming potential, gwp. Product information sorted by product type and name. Substitute refrigerants, called hydrofluorocarbons hfcs, have an odp of zero, but medium to high global warming potential gwp though still lower than phasedout cfcs. Low global warming potential refrigerants for commercial. However, when the different refrigerants are mixed by accident or deliberately, they will form mixtures that can be.
The higher the gwp number the more impact the refrigerant has on global warming. It has been found that hydrocarbons and ammonia are the least problematic with respect to above three properties. Gwp global warming potential degree to which a greenhouse gas ghg traps heat in the atmosphere. Refrigerant types, issues, trends and future options. Refrigerants are mixed r502 and freon hp refrigerants are chemically compatible with each other. Department of energys doe building technology office bto, a part of the office of energy efficiency and renewable energy, engaged navigant consulting, inc. The optimum replacements are refrigerants that are flammable, including hydrocarbons. Product information sorted by product type and name type product r number odp1 gwp2 cfc 12 1 high 10900 high 502 0,33 high 4657 high.
The ar5 values are the most recent, but the second assessment report 1995 and fourth. It has been found that hydrocarbons and ammonia are the least problematic with respect to. The business case for phasing down hfcs in room and vehicle air conditioners. Gwp is important but not the only measure of environmental impact. It is a natural refrigerant that has been used for over onehundred years and it will continue to be used for another onehundred years or more. Global warming potential gwp is a measure of the relative global warming effects of different gases. Flammability is classified based on a flame propagation test, lower flammability limit lfl. India october 2016 factsheet business case analysis cooling india with less warming. Pdf halogenated hydrocarbons with high ozone depletion potential odp were banned under montreal protocol 1987 due to their. Common refrigerants and their ozone depletion potential odp and global warming potential gwp are indicated below.
We estimate that shifting the 2030 world stock of room air conditioners from the low efficiency technology using highgwp refrigerants to higher efficiency technology and lowgwp refrigerants in parallel would save between 340790 gigawatts gw of peak load globally, which is roughly equivalent to avoiding 6801550 peak power plants of 500mw each. Benefits of leapfrogging to superefficiency and low global. Refrigerants r402a, r402b, and r404a properties, uses. In the future we will see more alternative refrigerants to hfcs due to the eu fgas regulation and future international phasedown of high global warming potential substances. Natural and synthetic refrigerants, global warming. Low global warming refrigerants for stationary air. Freon 407c exhibits similar performance to hcfc22 at air conditioning conditions, while freon 407a exhibits similar performance to r404a with lower capacity at low and. Research and development roadmap for nextgeneration low global warming potential refrigerants ii preface preface the u. However, when the different refrigerants are mixed by accident or deliberately, they will form mixtures that can be very difficult to separate. Please contact your respective danfoss representative to get the newest information. Hydrofluorocarbons hfcs, which are currently used as refrigerants in airconditioning ac systems, are potent greenhouse gases, with high values of global warming potential gwp. Jul 29, 20 curbing them is key to climatechange strategy oped. Assessment of commercially available energyefficient room.
Second, because of its superior thermodynamic properties, ammonia as a refrigerant requires less energy than other refrigerants when used in large industrial systems. With hfcs the big concern was global warming potential, or gwp. Energy and global warming impacts of hfc refrigerants and. Pdf refrigerant types, issues, trends and future options. Read online standards for lowglobal warming potential. It will help you understand current and future refrigerants and technologies, with focus on global warming potential, energy consumption, and system efficiency. Decision xix6, taken in 2007, to adjust the protocol to accelerate the phase out of. Impact of charge degradation on the life cycle climate performance of a residential air conditioning system an evaluation of the environmental impact of different commercial supermarket refrigeration systems using low global warming potential refrigerants. Global warming potential gwp is a measure of how much a given mass of a gas contributes to global. This table is adapted from the ipcc fifth assessment report, 2014 ar5i. Two new low gwp refrigerant molecules hfo1234yf, hfo1234ze have been identified. Secondly, since r744 has no ozone depletion potential and a global warming potential of only one you can be safe in assuming that carbon dioxide will never be phased down our across the world. Hfc refrigerants are green house gas or super pollutants.
Performance assessment of vapor compression systems utilizing. This text file should be in a comma separated value format. Improving the energy efficiency of room air conditioners racs will be a critical step toward reducing the energy, peak load, and total lifecycle emissions impacts of racs while transitioning to low global warming potential gwp refrigerants under the 2016 kigali amendment to the montreal protocol. Global warming potential, or gwp, is a measure of how destructive a climate pollutant is. Baxter oak ridge national laboratory oak ridge, tennessee sponsored by alternative fluorocarbons environmental acceptability study afeas u. Talking retrofit its only about existing systems that should be fitted with an alternative refrigerant. It is a mathematical method to assess the relationship between various chemicals.
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